Origin of room temperature broadband light emission and carrier dynamics in Ag ion-implanted silicon nanocrystals

Akhilesh K. Singh, Zygmunt Gryczynski, Arup Neogi

Research output: Contribution to journalArticle

9 Citations (Scopus)

Abstract

We studied the origin of broad band light emission in the Ultraviolet (UV) to the red from silicon nanoparticles fabricated using a single low energy (32 keV) silver ion implantation with a fluence of 5*1015 ions/cm2 in crystalline Si. It is found from a systematic study of the annealing carried out at certain temperatures that the spectral characteristics in the UV and blue region remains unchanged except for the enhancement of light emission intensity due to annealing. The annealing results in nucleation of Ag nanoclusters in the vicinity of Si nanoparticles which enhances the emission intensity. Time-resolved photoluminescence (TRPL) measurement demonstrates that the emission originates from both highly localized defect bound excitons at the nanoscale Si interface, as well as surface and interface traps associated with the increased surface area of the Si nanocrystals. The emission in the UV is due to interband transitions from localized excitonic states at the interface of Si/SiO2 or from the surface of Si nanocrystals. The radiative efficiency of the UV and the green emission from the Si nanoparticles can be modified by the localized plasmons interaction induced by the nucleation of Silver nanoparticles on controlled annealing of the samples. Broadband emission ranging from the UV to the red wavelength range can be obtained on Ag implanted onto a single silicon substrate.

Original languageEnglish
Pages (from-to)501-509
Number of pages9
JournalOptical Materials Express
Volume2
Issue number5
DOIs
StatePublished - 1 May 2012

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Light emission
Silicon
Nanocrystals
Annealing
Ions
Nanoparticles
Silver
Nucleation
Temperature
Plasmons
Nanoclusters
Excitons
Ion implantation
Photoluminescence
Crystalline materials
Wavelength
Defects
Substrates

Cite this

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abstract = "We studied the origin of broad band light emission in the Ultraviolet (UV) to the red from silicon nanoparticles fabricated using a single low energy (32 keV) silver ion implantation with a fluence of 5*1015 ions/cm2 in crystalline Si. It is found from a systematic study of the annealing carried out at certain temperatures that the spectral characteristics in the UV and blue region remains unchanged except for the enhancement of light emission intensity due to annealing. The annealing results in nucleation of Ag nanoclusters in the vicinity of Si nanoparticles which enhances the emission intensity. Time-resolved photoluminescence (TRPL) measurement demonstrates that the emission originates from both highly localized defect bound excitons at the nanoscale Si interface, as well as surface and interface traps associated with the increased surface area of the Si nanocrystals. The emission in the UV is due to interband transitions from localized excitonic states at the interface of Si/SiO2 or from the surface of Si nanocrystals. The radiative efficiency of the UV and the green emission from the Si nanoparticles can be modified by the localized plasmons interaction induced by the nucleation of Silver nanoparticles on controlled annealing of the samples. Broadband emission ranging from the UV to the red wavelength range can be obtained on Ag implanted onto a single silicon substrate.",
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Origin of room temperature broadband light emission and carrier dynamics in Ag ion-implanted silicon nanocrystals. / Singh, Akhilesh K.; Gryczynski, Zygmunt; Neogi, Arup.

In: Optical Materials Express, Vol. 2, No. 5, 01.05.2012, p. 501-509.

Research output: Contribution to journalArticle

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