Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates

Lajos Bencze; Laszlo Prokai

doi:10.1016/0022-328X(85)88060-8

Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates

Lajos Bencze, Laszlo Prokai

Institute for Healthy Aging

Research output: Contribution to journal › Article › peer-review

6 Scopus citations

Abstract

Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)₃Cl₂(AsPh₃)₂ and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.

Original language	English
Journal	Journal of Organometallic Chemistry
Volume	294
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(85)88060-8
State	Published - 8 Oct 1985

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title = "Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates",

abstract = "Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.",

author = "Lajos Bencze and Laszlo Prokai",

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AU - Bencze, Lajos

AU - Prokai, Laszlo

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N2 - Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.

AB - Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.

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JF - Journal of Organometallic Chemistry

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