Abstract
Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.
| Original language | English |
|---|---|
| Journal | Journal of Organometallic Chemistry |
| Volume | 294 |
| Issue number | 1 |
| DOIs | |
| State | Published - 8 Oct 1985 |
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Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates. / Bencze, Lajos; Prokai, Laszlo.
In: Journal of Organometallic Chemistry, Vol. 294, No. 1, 08.10.1985.Research output: Contribution to journal › Article
TY - JOUR
T1 - Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates
AU - Bencze, Lajos
AU - Prokai, Laszlo
PY - 1985/10/8
Y1 - 1985/10/8
N2 - Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.
AB - Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.
UR - http://www.scopus.com/inward/record.url?scp=4244184810&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(85)88060-8
DO - 10.1016/0022-328X(85)88060-8
M3 - Article
AN - SCOPUS:4244184810
VL - 294
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
SN - 0022-328X
IS - 1
ER -