Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates

Lajos Bencze, Laszlo Prokai

Research output: Contribution to journalArticle

6 Citations (Scopus)

Abstract

Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.

Original languageEnglish
JournalJournal of Organometallic Chemistry
Volume294
Issue number1
DOIs
StatePublished - 8 Oct 1985

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Carbonylation
Hydroformylation
Alkenes
carbenes
alkenes
Olefins
alcohols
Alcohols
Water
Carbon Monoxide
water
Carbon
Metals
Oxygen
carbon
oxygen
metals
carbene
ketene
2-norbornene

Cite this

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abstract = "Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.",
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AU - Prokai, Laszlo

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