Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates

Lajos Bencze; László Prókai

doi:10.1016/0022-328X(85)88060-8

Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates

Lajos Bencze, László Prókai

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Abstract

Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)₃Cl₂(AsPh₃)₂ and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.

Original language	English
Pages (from-to)	c5-c8
Journal	Journal of Organometallic Chemistry
Volume	294
Issue number	1
DOIs	https://doi.org/10.1016/0022-328X(85)88060-8
State	Published - 8 Oct 1985

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title = "Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates",

abstract = "Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.",

author = "Lajos Bencze and L{\'a}szl{\'o} Pr{\'o}kai",

year = "1985",

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T1 - Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates

AU - Bencze, Lajos

AU - Prókai, László

PY - 1985/10/8

Y1 - 1985/10/8

N2 - Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.

AB - Stoichiometric hydroformylation and carbonylation of norbornene takes place in the presence of W(CO)3Cl2(AsPh3)2 and water or alcohol via initial formation of carbene and ketene type intermediates followed by nucleophilic addition of water or alcohol or a hydrido-metal species to the carbon- oxygen double bond of the ketene.

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U2 - 10.1016/0022-328X(85)88060-8

DO - 10.1016/0022-328X(85)88060-8

M3 - Article

AN - SCOPUS:4244184810

VL - 294

SP - c5-c8

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

SN - 0022-328X

IS - 1

ER -

Novel mechanism for the carbonylation and hydroformylation of olefins via carbene and ketene type intermediates

Abstract

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