Mechanism of initiation of the metathesis of norbornene using W(CO) 3Cl2(AsPh3)2 as catalyst

Lajos Bencze, Anna Kraut-Vass, Laszlo Prokai

Research output: Contribution to journalArticle

64 Citations (Scopus)

Abstract

Low molecular-weight derivatives obtained during ring-opening polymerisation of norbornene using W(CO)3Cl2(AsPh 3)2 as catalyst indicate that a 2,3-hydrogen shift is a key step for the formation of the carbene initiator.

Original languageEnglish
Pages (from-to)911-912
Number of pages2
JournalJournal of the Chemical Society, Chemical Communications
Issue number13
DOIs
StatePublished - 1 Jan 1985

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Carbon Monoxide
Polymerization
Hydrogen
Molecular Weight
carbene
2-norbornene

Cite this

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title = "Mechanism of initiation of the metathesis of norbornene using W(CO) 3Cl2(AsPh3)2 as catalyst",
abstract = "Low molecular-weight derivatives obtained during ring-opening polymerisation of norbornene using W(CO)3Cl2(AsPh 3)2 as catalyst indicate that a 2,3-hydrogen shift is a key step for the formation of the carbene initiator.",
author = "Lajos Bencze and Anna Kraut-Vass and Laszlo Prokai",
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Mechanism of initiation of the metathesis of norbornene using W(CO) 3Cl2(AsPh3)2 as catalyst. / Bencze, Lajos; Kraut-Vass, Anna; Prokai, Laszlo.

In: Journal of the Chemical Society, Chemical Communications, No. 13, 01.01.1985, p. 911-912.

Research output: Contribution to journalArticle

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AB - Low molecular-weight derivatives obtained during ring-opening polymerisation of norbornene using W(CO)3Cl2(AsPh 3)2 as catalyst indicate that a 2,3-hydrogen shift is a key step for the formation of the carbene initiator.

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