Mechanism of initiation of the metathesis of norbornene using W(CO) 3Cl2(AsPh3)2 as catalyst

Lajos Bencze; Anna Kraut-Vass; László Prókai

doi:10.1039/C39850000911

Mechanism of initiation of the metathesis of norbornene using W(CO) ₃Cl₂(AsPh₃)₂ as catalyst

Lajos Bencze, Anna Kraut-Vass, László Prókai

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67 Scopus citations

Abstract

Low molecular-weight derivatives obtained during ring-opening polymerisation of norbornene using W(CO)₃Cl₂(AsPh ₃)₂ as catalyst indicate that a 2,3-hydrogen shift is a key step for the formation of the carbene initiator.

Original language	English
Pages (from-to)	911-912
Number of pages	2
Journal	Journal of the Chemical Society, Chemical Communications
Issue number	13
DOIs	https://doi.org/10.1039/C39850000911
State	Published - 1985

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title = "Mechanism of initiation of the metathesis of norbornene using W(CO) 3Cl2(AsPh3)2 as catalyst",

abstract = "Low molecular-weight derivatives obtained during ring-opening polymerisation of norbornene using W(CO)3Cl2(AsPh 3)2 as catalyst indicate that a 2,3-hydrogen shift is a key step for the formation of the carbene initiator.",

author = "Lajos Bencze and Anna Kraut-Vass and L{\'a}szl{\'o} Pr{\'o}kai",

year = "1985",

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T1 - Mechanism of initiation of the metathesis of norbornene using W(CO) 3Cl2(AsPh3)2 as catalyst

AU - Bencze, Lajos

AU - Kraut-Vass, Anna

AU - Prókai, László

PY - 1985

Y1 - 1985

N2 - Low molecular-weight derivatives obtained during ring-opening polymerisation of norbornene using W(CO)3Cl2(AsPh 3)2 as catalyst indicate that a 2,3-hydrogen shift is a key step for the formation of the carbene initiator.

AB - Low molecular-weight derivatives obtained during ring-opening polymerisation of norbornene using W(CO)3Cl2(AsPh 3)2 as catalyst indicate that a 2,3-hydrogen shift is a key step for the formation of the carbene initiator.

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DO - 10.1039/C39850000911

M3 - Article

AN - SCOPUS:37049098568

SN - 0022-4936

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JO - Journal of the Chemical Society, Chemical Communications

JF - Journal of the Chemical Society, Chemical Communications

IS - 13

ER -

Mechanism of initiation of the metathesis of norbornene using W(CO) ₃Cl₂(AsPh₃)₂ as catalyst

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