Hydroformylation of nitrogen-containing cyclic olefins via "in-situ" rhodium-phosphine catalysts

Katalin Prokai-Tatrai, S. Torös, B. Heil

Research output: Contribution to journalArticle

11 Scopus citations

Abstract

Hydroformylation of nitrogen-containing cyclic olefins (N-substituted nortropidines, N-methyl-1,2,3,6-tetrahydropyridine (THP) with rhodium-PR3 catalysts prepared "in situ" is reported. The nortropidines reacted rapidly when either trialkyl- or triaryl-type phosphines were used, and the regioselectivities were not significantly influenced by the nature of the phosphine. With the less basic THP the rates and selectivities were generally lower, and were influenced by the phosphine ligand and by the presence of added bases such as Et3N.

Original languageEnglish
Pages (from-to)231-236
Number of pages6
JournalJournal of Organometallic Chemistry
Volume315
Issue number2
DOIs
StatePublished - 11 Nov 1986

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