TY - JOUR
T1 - Hydroformylation of nitrogen-containing cyclic olefins via "in-situ" rhodium-phosphine catalysts
AU - Prokai-Tatrai, Katalin
AU - Torös, S.
AU - Heil, B.
PY - 1986/11/11
Y1 - 1986/11/11
N2 - Hydroformylation of nitrogen-containing cyclic olefins (N-substituted nortropidines, N-methyl-1,2,3,6-tetrahydropyridine (THP) with rhodium-PR3 catalysts prepared "in situ" is reported. The nortropidines reacted rapidly when either trialkyl- or triaryl-type phosphines were used, and the regioselectivities were not significantly influenced by the nature of the phosphine. With the less basic THP the rates and selectivities were generally lower, and were influenced by the phosphine ligand and by the presence of added bases such as Et3N.
AB - Hydroformylation of nitrogen-containing cyclic olefins (N-substituted nortropidines, N-methyl-1,2,3,6-tetrahydropyridine (THP) with rhodium-PR3 catalysts prepared "in situ" is reported. The nortropidines reacted rapidly when either trialkyl- or triaryl-type phosphines were used, and the regioselectivities were not significantly influenced by the nature of the phosphine. With the less basic THP the rates and selectivities were generally lower, and were influenced by the phosphine ligand and by the presence of added bases such as Et3N.
UR - http://www.scopus.com/inward/record.url?scp=0009185907&partnerID=8YFLogxK
U2 - 10.1016/0022-328X(86)80440-5
DO - 10.1016/0022-328X(86)80440-5
M3 - Article
AN - SCOPUS:0009185907
SN - 0022-328X
VL - 315
SP - 231
EP - 236
JO - Journal of Organometallic Chemistry
JF - Journal of Organometallic Chemistry
IS - 2
ER -