Hydroformylation of methyl methacrylate via "in-situ" phosphinerhodium catalysis

K. Prókai-Tátrai; S. Torös; B. Heil

doi:10.1016/0022-328X(87)85100-8

Hydroformylation of methyl methacrylate via "in-situ" phosphinerhodium catalysis

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Abstract

It has been shown that in hydroformulation of methyl methacrylate with rhodium phosphine catalysts prepared "in situ" the regioselectivity is very sensitive not only to the reaction conditions but also to the basicity of the phosphine and to the presence of added Et₃N. At low P/Rh ratio chlororhodium species are catalytically active. No side reactions have been detected.

Original language	English
Pages (from-to)	331-335
Number of pages	5
Journal	Journal of Organometallic Chemistry
Volume	332
Issue number	3
DOIs	https://doi.org/10.1016/0022-328X(87)85100-8
State	Published - 6 Oct 1987

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abstract = "It has been shown that in hydroformulation of methyl methacrylate with rhodium phosphine catalysts prepared {"}in situ{"} the regioselectivity is very sensitive not only to the reaction conditions but also to the basicity of the phosphine and to the presence of added Et3N. At low P/Rh ratio chlororhodium species are catalytically active. No side reactions have been detected.",

author = "K. Pr{\'o}kai-T{\'a}trai and S. Tor{\"o}s and B. Heil",

year = "1987",

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AU - Prókai-Tátrai, K.

AU - Torös, S.

AU - Heil, B.

PY - 1987/10/6

Y1 - 1987/10/6

N2 - It has been shown that in hydroformulation of methyl methacrylate with rhodium phosphine catalysts prepared "in situ" the regioselectivity is very sensitive not only to the reaction conditions but also to the basicity of the phosphine and to the presence of added Et3N. At low P/Rh ratio chlororhodium species are catalytically active. No side reactions have been detected.

AB - It has been shown that in hydroformulation of methyl methacrylate with rhodium phosphine catalysts prepared "in situ" the regioselectivity is very sensitive not only to the reaction conditions but also to the basicity of the phosphine and to the presence of added Et3N. At low P/Rh ratio chlororhodium species are catalytically active. No side reactions have been detected.

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DO - 10.1016/0022-328X(87)85100-8

M3 - Article

AN - SCOPUS:0007946932

SN - 0022-328X

VL - 332

SP - 331

EP - 335

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

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ER -

Hydroformylation of methyl methacrylate via "in-situ" phosphinerhodium catalysis

Abstract

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