Hydroformylation of methyl methacrylate via "in-situ" phosphinerhodium catalysis

Katalin Prokai-Tatrai, S. Torös, B. Heil

Research output: Contribution to journalArticle

9 Scopus citations

Abstract

It has been shown that in hydroformulation of methyl methacrylate with rhodium phosphine catalysts prepared "in situ" the regioselectivity is very sensitive not only to the reaction conditions but also to the basicity of the phosphine and to the presence of added Et3N. At low P/Rh ratio chlororhodium species are catalytically active. No side reactions have been detected.

Original languageEnglish
Pages (from-to)331-335
Number of pages5
JournalJournal of Organometallic Chemistry
Volume332
Issue number3
DOIs
StatePublished - 6 Oct 1987

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