Effect of ionic liquids on the conformation of a porphyrin-based viscometer

Laramie P. Jameson; Joseph D. Kimball; Zygmunt Gryczynski; Milan Balaz; Sergei V. Dzyuba

doi:10.1039/c3ra43001d

Effect of ionic liquids on the conformation of a porphyrin-based viscometer

Laramie P. Jameson, Joseph D. Kimball, Zygmunt Gryczynski, Milan Balaz, Sergei V. Dzyuba

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22 Scopus citations

Abstract

Structure of the cationic and anionic counterparts of ionic liquids has a significant impact on the conformational bias of the porphyrin rotor; an apparent correlation between the conformation and the viscosity of ionic liquids was noted, albeit it was found to be distinct and more complex from that found in molecular solvents.

Original language	English
Pages (from-to)	18300-18304
Number of pages	5
Journal	RSC Advances
Volume	3
Issue number	40
DOIs	https://doi.org/10.1039/c3ra43001d
State	Published - 28 Oct 2013

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title = "Effect of ionic liquids on the conformation of a porphyrin-based viscometer",

abstract = "Structure of the cationic and anionic counterparts of ionic liquids has a significant impact on the conformational bias of the porphyrin rotor; an apparent correlation between the conformation and the viscosity of ionic liquids was noted, albeit it was found to be distinct and more complex from that found in molecular solvents.",

author = "Jameson, {Laramie P.} and Kimball, {Joseph D.} and Zygmunt Gryczynski and Milan Balaz and Dzyuba, {Sergei V.}",

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AU - Jameson, Laramie P.

AU - Kimball, Joseph D.

AU - Gryczynski, Zygmunt

AU - Balaz, Milan

AU - Dzyuba, Sergei V.

PY - 2013/10/28

Y1 - 2013/10/28

N2 - Structure of the cationic and anionic counterparts of ionic liquids has a significant impact on the conformational bias of the porphyrin rotor; an apparent correlation between the conformation and the viscosity of ionic liquids was noted, albeit it was found to be distinct and more complex from that found in molecular solvents.

AB - Structure of the cationic and anionic counterparts of ionic liquids has a significant impact on the conformational bias of the porphyrin rotor; an apparent correlation between the conformation and the viscosity of ionic liquids was noted, albeit it was found to be distinct and more complex from that found in molecular solvents.

UR - http://www.scopus.com/inward/record.url?scp=84884863592&partnerID=8YFLogxK

U2 - 10.1039/c3ra43001d

DO - 10.1039/c3ra43001d

M3 - Article

AN - SCOPUS:84884863592

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VL - 3

SP - 18300

EP - 18304

JO - RSC Advances

JF - RSC Advances

IS - 40

ER -

Effect of ionic liquids on the conformation of a porphyrin-based viscometer

Abstract

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