A comparison of acetyl- and methoxycarbonylnitrenes by computational methods and a laser flash photolysis study of benzoylnitrene

Keyphrases

• Acetyl 100%
• Computational Methods 100%
• Laser Flash Photolysis 100%
• Nitrenes 100%
• Azides 100%
• Methanol 66%
• Bimolecular Reaction 66%
• Curtius Rearrangement 66%
• CBS-QB3 66%
• Oxygen Atom 66%
• Singlet State 66%
• Activation Energy 66%
• Singlet 33%
• Carbonyl 33%
• Acetonitrile 33%
• Cyclohexane 33%
• CCSD(T) 33%
• Triplet State 33%
• Density Functional Theory 33%
• Singlet Carbene 33%
• Reaction Rate Constant 33%
• Benzyl Azide 33%
• Methyl Groups 33%
• Triplet Ground State 33%
• Activation Free Energy 33%
• Ethylene 33%
• Weak Interactions 33%
• Near-zero Energy 33%
• Entropic Factors 33%
• Chemical Difference 33%
• Pyrolysis 33%
• Water 4.0 33%
• Related Compounds 33%
• Reactivity Difference 33%
• Transition State 33%
• Nitrogen Extrusion 33%
• 1-hexene 33%
• N-containing Compounds 33%
• Free Energy Barrier 33%
• Propane 33%
• Methoxycarbonyl 33%
• Pentane 33%
• Isomerization 33%
• Reaction Rate 33%
• Alkenes 33%

Chemistry

• Acetyl 100%
• Flash Photolysis 100%
• Azide 100%
• Methanol 50%
• Reaction Activation Energy 50%
• Curtius Rearrangement 50%
• Bimolecular Reaction 50%
• Oxygen Atom 50%
• Ground State 25%
• Acetonitrile 25%
• Cyclohexane 25%
• Transition State 25%
• 1-Hexene 25%
• Reaction Rate Constant 25%
• Isomerization 25%
• CCSD 25%
• Triplet State 25%
• Methyl Group 25%
• Energy Barrier 25%
• Pyrolysis 25%
• Pentane 25%
• Alkene 25%
• Density Functional Theory 25%
• Free Energy of Activation 25%
• Singlet State 25%
• Triplet Ground State 25%
• Ethylene 25%
• Carbene 25%
• Free Energy 25%